論文・著書

著書

  • 錯体化学選書「有機金属化学」(三共出版)中沢 浩・小坂田耕太郎編,上野圭司,岡﨑雅明,河野泰朗,松坂裕之,水田勉共著,2010年
  • 無機化学命名法-IUPAC2005年勧告-日本化学会 化合物命名法委員会訳著、東京化学同人、2010年
  • 基本無機化学 第2版、荻野 博、飛田博実、岡﨑雅明、東京化学同人、2006年
  • 基本無機化学、荻野 博、飛田博実、岡﨑雅明、東京化学同人、2000年

論文

2016年

2014年

2013年

2012年

2011年

2010年

  • Facile 1,2-Migration of a Methyl Group on a {Dimethoxy(methyl)silyl}tungsten Complex: Formation of a Base-Stabilized (Dimethoxysilylene)(methyl) Complex
    Eiji Suzuki, Takashi Komuro, Yuto Kanno, Masaaki Okazaki, Hiromi Tobita, Organometallics,2010, 29, 5296-5300.
  • Synthesis and structures of platinum diphenylacetylene and dithiolate complexes bearing diphosphinidenecyclobutene ligands (DPCB-Y)
    Yumiko Nakajima, Mitsuharu Nakatani, Kyohei Hayashi, Yu Shiraishi, Ryo Takita, Masaaki Okazaki, and Fumiyuki Ozawa New J. Chem.,2010, 34, 1713-1722.
  • Synthesis and Characterization of κ2C,N-N-Silyliminoacyl Tungsten Complexes Cp*(CO)2W{κ2C,N-C(R)?NSiR'3} [R = Me, Et, i-Pr, t-Bu; R'3 = (p-Tol)2Me, (p-Tol)3, Et3; Cp* = η5-C5Me5]: Thermally Induced Carbon?Carbon Bond Cleavage of Their Iminoacyl Ligands
    Eiji Suzuki, Takashi Komuro, Yuto Kanno, Masaaki Okazaki and Hiromi Tobita Organometallics, 29, 1839-1848 (2010).
  • 四鉄-四炭素相乗系錯体の化学
    岡﨑雅明 触媒52巻4号, 236?242.

2009年

  • Redox-Active Phosphorus Ligands Bearing a [4Fe-4C] Core Substituent
    Masaaki Okazaki, Ken-ichi Yoshimura, Masato Takano, and Fumiyuki Ozawa Organometallics, 2009, 28, 7055-7058.
  • Synthesis and Characterization of DMAP-Stabilized Aryl(silylene) Complexes and (Arylsilyl)(DMAP) Complexes of Tungsten: Mechanistic Study on the Interconversion between These Complexes via 1,2-Aryl Migration
    Eiji Suzuki, Takashi Komuro, Masaaki Okazaki, Hiromi Tobita Organometallics, 28, 1791-1799 (2009).
  • Redox-responsive Recombination of Carbon?Carbon Bonds on Flexible Tetrairon Cores
    Masaaki Okazaki, Masato Takano, Fumiyuki Ozawa J. Am. Chem. Soc., 131, 1684-1685 (2009).
  • Synthesis, Structures, and Reactions of Dirhodium Complexes Bearing 1,2-Diphenyl-3,4-diphosphinidenecyclobutene Ligand (DPCB)
    Masaaki Okazaki, Akito Hayashi, Ching-Feng Fu, Shiuh-Tzung Liu, and Fumiyuki Ozawa, Organometallics, 28, 902-908 (2009).

2008年

  • Recombination of an Fe?Si?P Linkage to an Fe?P?Si Linkage through an Isolable Intermediate Phosphasilaferracyclopropane
    Masaaki Okazaki, Takahiko Yoshitomi, Junpei Naito, Akira Sato, Takashi Komuro, Hiromi Tobita, J. Am. Chem. Soc., 130, 17674?17675 (2008).
  • Synthesis and Ligand Properties of 1-Phosphaethenyl-2-phosphanylferrocenes
    Ryo Takita, Yuko Takada, Rader S. Jensen, Masaaki Okazaki, Fumiyuki Ozawa, Organometallics, 27, 6279?6285 (2008).
  • Synthesis and Structures of Platinum(0) Alkyne Complexes with Extended pi-Conjugated Systems
    Kyohei Hayashi, Mitsuharu Nakatani, Akito Hayashi, Masato Takano, Masaaki Okazaki, Kozo Toyota, Masaaki Yoshifuji, Fumiyuki Ozawa, Organometallics, 27, 1970-1972 (2008).
  • A New Hydrosilylation Reaction of Arylacetylene Accompanied by C?H Bond Activation Catalyzed by a Xantsil Ruthenium Complex
    Hiromi Tobita, Nobukazu Yamahira, Keisuke Ohta, Takashi Komuro, Masaaki Okazaki, Pure Appl. Chem., 80, 1155-1160 (2008).
  • Synthesis and Reactions of Diphosphinidenecyclobutene Ruthenium Complexes Relevant to Catalytic Hydrosilylation of Terminal Alkynes
    Akito Hayashi, Takahiko Yoshitomi, Kazutoshi Umeda, Masaaki Okazaki, Fumiyuki Ozawa, Organometallics, 27, 1970-1972 (2008).
  • [Ru(xantsil)(CO)(h6-Toluene)]: Synthon for a Highly Unsaturated Ruthenium(II) Complex through Facile Dissociation of the Toluene Ligand [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]
    Masaaki Okazaki, Nobukazu Yamahira, Jim Josephus Gabrillo Minglana, Takashi Komuro, Hiroshi Ogino, and Hiromi Tobita, Organometallics, 27, 918?926 (2008).

2007年

  • Iron, Ruthenium, and Osmium Complexes Supported by the Bis(silyl) Chelate Ligand (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl): Synthesis, Characterization, and Reactivity
    Jim Josephus G. Minglana, Masaaki Okazaki, Kenji Hasegawa, Lung-Shiang Luh, Nobukazu Yamahira, Takashi Komuro, Hiroshi Ogino, and Hiromi Tobita, Organometallics, 26, 5859-5866 (2007).
  • Synthesis, Structures, and Catalytic Properties of Late Transition Metal 2,6-Bis(2-phosphaethenyl)pyridine Complexes
    Akito Hayashi, Masaaki Okazaki, Fumiyuki Ozawa, Rika Tanaka, Organometallics, 26, 5246-5249 (2007).
  • Three- and Five-Membered W/C/N Metallacycles Formed by Incorporation of Acetonitrile Molecules into Silyltungsten Intermediates
    Eiji Suzuki, Takashi Komuro, Masaaki Okazaki, Hiromi Tobita, Organometallics, 26, 4379-4382 (2007).
  • Cationic Iridium(III) Complexes Bearing Phosphaalkene and 2-Pyridylphenyl Ligands
    Akito Hayashi, Takeshi Ishiyama, Masaaki Okazaki, Fumiyuki Ozawa, Organometallics, 26, 3708-3712 (2007).
  • Structure and Properties of Three- and Six-Membered Metallacycles Composed of Iron, Germanium, and Sulfur Atoms
    Masaaki Okazaki, Hiromitsu Kimura, Takashi Komuro, Hiroshi Okada, Hiromi Tobita, Chem. Lett. 36, 990-991 (2007).
  • Synthesis and Catalytic Properties of Cationic Palladium(II) and Rhodium(I) Complexes Bearing Diphosphinidinecyclobutene Ligand
    Rader S. Jensen, Kazutoshi Umeda, Masaaki Okazaki, Fumiyuki Ozawa, Masaaki Yoshifuji, J. Organomet. Chem. 692, 286-294 (2007).

2006年

  • Insertion of Pyridine into an Iron?Silicon Bond and Photochemical Conversion of the Insertion Product Cp*(OC)Fe{η3(C,C,C)-C5H5NSiMe2NPh2} to a Sandwich Compound
    Masatoshi Iwata, Masaaki Okazaki, Hiromi Tobita, Organometallics 25, 6115-6124 (2006).
  • 遷移金属-ケイ素錯体の化学, 岡﨑雅明, ケイ素化学協会誌, 23, 39 (2006). 元素相乗型錯体の創製とその機能,
    岡﨑雅明, Bulletin of Japan Society of Coordination Chemistry, 48, 86-87 (2006).

2005年

  • Synthesis and Structure of a Base-Stabilized Silyl(silylene)tantalum Complex
    Hidenori Koshikawa, Masaaki Okazaki, Shun-ichi Matsumoto, Keiji Ueno, Hiromi Tobita, Hiroshi Ogino, Chem. Lett., 34, 1412-1413 (2005).
  • Reversible 1,2-Migration of Aryl Groups on Silyl Ligands: Formation and Properties of Silylenetungusten Complexes Stabilized by an External Base
    Eiji Suzuki, Masaaki Okazaki, Hiromi Tobita, Chem. Lett., 34, 1026-1027 (2005).
  • Synthesis and Property of BrCCH- and BrCCBr-Coordinated Tetrairon Clusters
    Masaaki Okazaki, Masato Takano, Ken-ichi Yoshimura, J. Orgaomet. Chem., 690, 5318-5332 (2005). (Special issue for Young Scientists in Organometallic Chemistry 2005).
  • Reactivity of Phosphasilametallacyclopropane Toward Substrates with Polarized E?H Bonds (E = O, N, S, and P): Formation and Structures of Ring-Opening Products
    Masaaki Okazaki, Kyeong A Jung, Hiromi Tobita, Organometallics, 24, 659-664 (2005).
  • Regioselective Silylphosphination of Methyl Vinyl Ketone with Complexes Containing Cyclic and Linear Iron?Silicon?Phosphorus Reacting Sites
    Masaaki Okazaki, Kyeong A Jung, Hiromi Tobita, Chem. Commun., 2005, 912 ? 914.

2004年

  • Ru(xantsil)(CO)(PCy3): Facile Generation of a Coordinatively Unsaturated Ruthenium(II) Complex Bearing 14 Valence Electrons [xantsil = (9,9-Dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]
    Masaaki Okazaki, Nobukazu Yamahira, Jim Josephus Gabrillo Minglana, Hiromi Tobita, Organometallics, 23, 4531-4533 (2004).
  • Cluster Core Expansion through Incorporation of Transition-Metal Fragments or an Alkyne Molecule into an Incomplete Cubane-Type Fe2RuS4 Cluster
    Masaaki Okazaki, Atsushi Sakuma, Hiromi Tobita, Hiroshi Ogino, Chem. Lett., 33, 1130-1131 (2004).
  • Stepwise Bromination of Two Acetylene Molecules on a Butterfly-Type Tetrairon Core and Reactivity of the Resulting Bromoacetylene Fragment Toward Nucleophiles
    Masato Takano, Masaaki Okazaki, Hiromi Tobita, J. Am. Chem. Soc., 126, 9190-9191 (2004).
  • Stepwise Reduction of Four Carbonyl Ligands in (h5-C5H4Me)4Fe4(m3-CO)4 to Produce Clusters Containing m3-Methylidyne and/or Acetylene Ligands
    Masaaki Okazaki, Takeo Ohtani, Masato Takano, Hiroshi Ogino, Organometallics, 23, 4055-4061 (2004).
  • Alkoxyhydrosilanes as Sources of Silylene Ligands: Novel Approaches to Transition Metal-Silylene Complexes
    Takahiro Sato, Masaaki Okazaki, Hiromi Tobita, Chem. Lett., 33, 868-869 (2004).
  • Phosphasilaferracyclopropane: An Activator of Small Molecules Having Polarized Single, Double, and Aromatic Unsaturated Bonds
    Masaaki Okazaki, Kyeong A Jung, Kazuyuki Satoh, Hiroshi Okada, Junpei Naito, Tadahiro Akagi, Hiromi Tobita, Hiroshi Ogino, J. Am. Chem. Soc., 126, 5060-5061 (2004).
  • Dimerization of Phosphasilaferracycles: Formation and Structures of Isomeric Fe2Si2P2 Six-Membered Metallacylcles
    Masaaki Okazaki, Kazuyuki Satoh, Kyeong A Jung, Hiromi Tobita, Hiroshi Ogino, Organometallics, 23, 1971-1973 (2004).
  • Reversible Cleavage and Recombination of Acetylenic Carbon?Carbon Bond on a Tetrairon Cluster Coupled with Two-Electron Redox Reaction
    Masaaki Okazaki, Takeo Ohtani, Hiroshi Ogino, J. Am. Chem. Soc., 126, 4104-4105 (2004).
  • 水素を置換基としてもつシリレン錯体の合成とオレフィンのヒドロシリル化反応への応用、
    岡﨑雅明, Organometallic News「有機金属ハイライト」, No.1, 23 (2004).

2003年

  • Reactivity of Silylene Complexes
    Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino, Dalton Trans., 2003, 493-506.
  • Synthesis and Structure of k2(Si,P)-(Phosphinomethyl)silyl Iridium(III) Complexes
    Masaaki Okazaki, Masatoshi Iwata, Hiromi Tobita, Hiroshi Ogino, Science Reports Tohoku University, Series 1 (Chemistry), 80, 11-19 (2003).
  • Insertion of Pyridine into an Iron?Silicon Bond: Structure of the Product Cp*(CO)Fe{h3(C,C,C)-C5H5NSiMe2NPh2}
    Masatoshi Iwata, Masaaki Okazaki, Hiromi Tobita, Chem. Commun., 2003, 2744-2745.
  • Facile Isomerization of Tungsten Silyl Complex to Silylene Complex via a-Migration of Substituent
    Masaaki Okazaki, Eiji Suzuki, Norito Miyajima, Hiromi Tobita, Hiroshi Ogino, Organometallics, 22, 4463-4635 (2003).
  • Synthesis, Structure, and Reactivity of Hydridobis(silylene)ruthenium(IV)-xantsil Complexes [xantsil = (9,9-Dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]: a Stabilized Form of Key Intermediates in the Catalytic Oligomerization/Deoligomerization of Hydrosilanes
    Masaaki Okazaki, Jim Josephus G. Minglana, Nobukazu Yamahira, Hiromi Tobita, Hiroshi Ogino, Can. J. Chem., 81, 1350-1358 (2003).
  • Photochemistry of a Tellurosilyl(carbonyl)iron(II) Complex: Generation of a Novel Te-Si-Fe Three-Membered Cyclic Intermediate
    Hiroshi Okada, Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino, Chem. Lett., 32, 876-877 (2003).
  • Reactions of M[(h5-C5Me5)Fe(CO)2] with ClSiMe2NR2 in THF, Et2O and Toluene (M = Li and K, R = Me, Et, iPr and Ph)
    Masaaki Okazaki, Masatoshi Iwata, Hiromi Tobita, Hiroshi Ogino, Dalton Trans., 2003, 1114-1120.
  • Synthesis, Structure, and Reactivity of Novel Iron(II) Complexes with a Five-Membered Chelate Ligand k2 (Si,N)-SiMe2O(2-C5H4N)
    Takahiro Sato, Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino, J. Organomet. Chem., 669, 189-199 (2003).

2002年

  • Synthesis and Structures of One- and Two-Electron Oxidized Forms of Bis(acetylene)tetrairon Clusters Cp’4Fe4(HCCH)2 (Cp’ = Cp, h5-C5H4Me)
    Masaaki Okazaki, Takeo Ohtani, Masato Takano, Hiroshi Ogino, Inorg. Chem., 41, 6726-6730 (2002).
  • Coordinatively Unsaturated Ru(II) Species Ru(xantsil)(CO): An Active Catalyst for Oligomerization/Deoligomerization of HSiMe2SiMe3 and a Precursor of a Stabilized Form of Silyl(silylene) Intermediates [xantsil = (9,9-Dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]
    Jim Josephus G. Minglana, Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino, Chem. Lett., 2002, 406-407.
  • Synthesis, Structure, and Reactivity of {(2-Phosphinoethyl)silyl}rhodium(I) Complex Rh[(k2-Si,P)-Me2Si(CH2)2PPh2](PMe3)n (n = 2, 3)
    Masaaki Okazaki, Shin Ohshitanai, Hiromi Tobita, Hiroshi Ogino, J. Chem. Soc., Dalton Trans., 2002, 2061-2068.
  • Convenient Preparation of Li[(h5-C5Me5)M(CO)2] (M = Ru, Fe) by the Reaction of (h5-C5Me5)M(CO)2H with n-BuLi
    Masaaki Okazaki, Kazuyuki Satoh, Tadahiro Akagi, Masatoshi Iwata, Kyeong A Jung, Rie Shiozawa, Hiroshi Ogino, Keiji Ueno, Hiromi Tobita, Hiroshi Ogino, J. Organomet. Chem., 645, 201-205 (2002).
  • Synthesis and Reactivity of (Phosphinoalkyl)silyl Complexes
    Masaaki Okazaki, Shin Ohshitanai, Masatoshi Iwata, Hiromi Tobita, Hiroshi Ogino, Coord. Chem. Rev., 226, 167-178 (2002).

2001年

  • Dehydrogenative Coupling of Monohydrosilanes Mediated by (2-Phosphinoethyl)silylrhodium(I) Complex
    Masaaki Okazaki, Shin Ohshitanai, Hiromi Tobita, Hiroshi Ogino, Chem. Lett., 2001, 952-953.
  • Cluster Construction by Reactions of an Isomeric Pair of Trinuclear Clusters Containing a Tetrathiotungstate Fragment [{Cp’Ru(CO)}2{W(m-S)4}] and [{Cp’Ru(CO)}2{W(=S)(m3-S)(m-S)2}] (Cp’ = h5-C5Me5, h5-C5Me4Et) with Platinum Complexes
    Yuki Masahiro, Masaaki Okazaki, Hiroshi Ogino, Organometallics, 20, 1762-1769 (2001).
  • シリレン錯体の反応性, 岡﨑雅明、荻野 博, 化学工業、52, 973-979 (2001).

2000年

  • Synthesis and Structure of Bis(silylene)iron Complexes Containing New Six-Membered Chelate Rings
    Hiromi Tobita, Takahiro Sato, Masaaki Okazaki, Hiroshi Ogino, J. Organomet. Chem., 611, 314-322 (2000).
  • Cluster Synthesis by the Reactions of [Cp’2M2S4] with Metal Complexes (Cp’ = Cp and Substituted Cyclopentadienyl Ligands, M = Fe, Ru)
    Masaaki Okazaki, Masahiro Yuki, Katsuaki Kuge, Hiroshi Ogino, Coord. Chem. Rev., 198, 367-378 (2000).

1999年以前

  • Extremely Facile Arene Exchange on a Ruthenium(II) Complex Having a Novel Bis(silyl) Chelate Ligand (9,9-Dimethylxanthene-4,5-diyl)bis(dimethylsilyl) (Xantsil)
    Hiromi Tobita, Kenji Hasegawa, Jim Josephus Gabrillo Minglana, Lung-Shiang Luh, Masaaki Okazaki, Hiroshi Ogino, Organometallics, 18, 2058-2060 (1999).
  • Cluster Synthesis by the Reactions of [Cp’2Fe2S4] with transition-metal complexes (Cp’ = C5Me5, 1, 3-C5H3(SiMe3)2)
    Masahiro Yuki, Katsuaki Kuge, Masaaki Okazaki, Toshiaki Mitsui, Shinji Inomata, Hiromi Tobita, Hiroshi Ogino, Inorg. Chim. Acta., 291, 395-402 (1999).
  • Synthesis and Structures of Two Isomeric Pairs of Tetrathiotungstate Clusters, [{Cp*Ru(CO)}2(WS4){W(CO)4}] and [{Cp*Ru(CO)}2(WS4)] (Cp* = h5-C5Me5), by Reaction of [Cp*2Ru2S4] with [W(CO)3(NCMe)3]
    Masahiro Yuki, Masaaki Okazaki, Shinji Inomata, Hiroshi Ogino, Organometallics, 18, 3728-3736 (1999).
  • Stepwise Construction of Clusters Containing Ru2PtWS4 and Ru2Pt2WS4 Cores by the Thermal Reaction of [{Cp*Ru(CO)}2(WS4)] (Cp* = h5-C5Me5) with [PtMe2(cod)] (cod = 1,5-cyclooctadiene)
    Masahiro Yuki, Masaaki Okazaki, Hiroshi Ogino, Chem. Lett., 1999, 649-650.
  • Reductive Coupling of Carbonyl Ligands on a Cubane-Type Tetrairon Cluster [Cp4Fe4(CO)4] or [(MeC5H4)4Fe4(CO)4] to Give an Acetylene-Coordinated Cluster [Cp4Fe4(HCoCH)2] or [(MeC5H4)4Fe4(HCoCH)2]
    Masaaki Okazaki, Takeo Ohtani, Shinji Inomata, Naohiko Tagaki, Hiroshi Ogino, J. Am. Chem. Soc., 120, 9135-9138 (1998).
  • Formation of Isomeric Tetrathiotungstate Clusters [{Cp*Ru(CO)2}2(WS4){W(CO)4}] by the Reaction of [Cp*2Ru2S4] with [W(CO)3(MeCN)3]
    Masahiro Yuki, Masaaki Okazaki, Shinji Inomata, Hiroshi Ogino, Angew. Chem. Int. Ed. Engl., 37, 2126-2128 (1998).
  • Photon-, Reductant-, and Oxidant-Induced Substitution of a CO Ligand on closo-[Cp*2Fe3S2(CO)3] (Cp* = h5-C5Me5),
    Masahiro Yuki, Toshiaki Mitsui, Shinji Inomata, Masaaki Okazaki, Hiroshi Ogino, Chem. Lett., 1998, 561-562.
  • Thermal Reaction of Ethyl(hydrido)(silyl)iridium(III) Complex ?Formation of a Silyl(ethene)iridium(I) Complex?
    Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino, Chem. Lett., 1998, 69-70.
  • Thermal Reactions of Alkyl(hydrido)(hydrosilyl)iridium(III) Complexes: Generation of a Hydrido(silylene)iridium(I) Species via the Reductive Elimination of Alkane and 1,2-H-Shift from the Silicon Atom to the Ir(I) Metal Center
    Masaaki Okazaki, Hiromi Tobita, Yasuro Kawano, Shinji Inomata, Hiroshi Ogino, J. Organomet. Chem., 553, 1-13 (1998).
  • Quantitative Transfer of a Methyl Group from a Methyl(hydrido)iridium Complex to H3SiR (R = n-butyl, pentyl, hexyl) to Give H2MeSiR and a Dihydridoiridium Complex,
    Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino, J. Chem. Soc., Dalton Trans., 1997, 3531-3533.
  • Iridium-Catalyzed Redistribution of Hydrodisilanes via a Silyl(silylene)iridium(III) Complex: Synthesis of a Donor-Stabilized Silyl(silylene)iridium(III) Complex
    Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino, Chem. Lett., 1997, 437-438.
  • Synthesis and Structure of the {(2-Phosphinoethyl)silyl}tris(tertiary phosphine)iridium(I) Complex Ir{h2-Me2Si(CH2)2PPh2}(PMe3)3
    Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino, Organometallics, 15, 2790-2793 (1996).
  • Generation of Hydrido(silylene)iridium(I) Complex via [1,2] H Shift from the Silicon Atom to the Iridium(I) Metal Center
    Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino, Chem. Lett., 1996, 477-478.
  • Light and Heat-Induced Geometric Isomerization of Chloro(hydrido)iridium(III) Complex Containing a (2-Phosphinoethyl)silyl Chelate Ligand
    Masaaki Okazaki, Yasuro Kawano, Hiromi Tobita, Shinji Inomata, Hiroshi Ogino, Chem. Lett., 1995, 1005-1006.