宮本　量 (MIYAMOTO, Ryo):　主な研究分野 (Research Works)

The School of Athene

専門分野 (Research interest)

卒業研究等について

遷移金属錯体のための電子常磁性共鳴法

分子軌道計算のための Z-matrix Editor ``KUMI'', 分子量・元素分析値計算プログラム ``xmolwt''

学術論文 (Academic Papers)

• ``Composition and antimicrobial activity of the essential oil and water extract from Japanese wild Rosa rugosa''
  M. Nagaki, Y. Goto, T. Narita, J. Kawakami, R. Miyamoto Trans. Mater. Res. Soc. Jpn., (2011), 36, 517-521.

• ``Theoretical Study of Substituent Effects on Electronic and Structural Properties of the 2,4-Diamino-5-para-substituted-phenyl-6-ethyl-pyrimidines''
  B.A. Saleh, H.A. Abood, R. Miyamoto, M. Bortoluzzi, J. Iran. Chem. Soc., (2011), 8, 653-661.

• ``TD-DFT Study on the Fluorescent Chemosensor for Hg²⁺, 2-(Benzo-d-thiazol-2-yl)quinoline''
  Ryo MIYAMOTO, Jun KAWAKAMI, Rie OHTAKE, Masahiko NAGAKI, Shunji ITO, J. Mol. Struct., (2011), 991, 73-78.

• ``Solvent control on the structural versatility and properties of manganese(II) complexes surrunded by the flexible hinge-like ligand''
  Ryuta Ishikawa, Koichi Yamada, Seigo Yamauchi, Ryo Miyamoto, Satoshi Kawata, Inorg. Chem. Commun., (2010), 13, 636-640.

• ``Substrate specificities of wild- and mutated-type farnesyl diphosphate synthases with artificial substrate homologs''
  M. Nagaki, K. Miyata, J. Kawakami, R. Miyamoto, Y. Maki, H. Sagami, T. Koyama, Trans. MRS-J, (2009), 34, 533-536.

• ``2-(Benzo-d-thiazol-2-yl)quinoline as a Fluorescent Chemosensor Material for Hg(II)''
  J. Kawakami, R. Ohtake, R. Miyamoto, M. Nagaki, and S. Ito, Trans. MRS-J, (2008), 33, 9-11.

• ``IUPAC--NIST Solubility Data Series 85. Transition and 12 to 14 Main Group Metals, Lanthanide, Actinide and Ammonium Halates''
  Hiroshi Miyamoto (Editor, Evaluator), Ryo Miyamoto (Editor, Evaluator), Cezary Guminski (Editor), Mark Salomon (Editor), Christo Balarew (Compiler), E. V. Zagnit'ko (Compiler), Jitka Eysseltova (Compiler), and Jean-Jacques Counioux (Compiler), J. Phys. Chem. Ref. Data, (2008), 37, 933-1118.

• ``XAFS Study on the Local Structure of Some Lanthanoid(III) Complexes'' S. Sudoh, T. Miyanaga, R. Miyamoto,
  AIP Conf. Proc., (2007), 882, 440-442. #Proccedings on XAFS 13, AIP

• ``A New Series of Radical-Triplet Pairs: Modulation of Radical-Triplet Interaction by a Counter Ion''
  L. Maretti, I. S. M. Saiful, T. Kajiwara, R. Miyamoto, Y. Ohba, S. Yamauchi, Mol. Phys., (2006), 104, 1619-1626.

• ``Time-dependent DFT Study of Emission Mechanism of 8-Hydroxyquinoline Derivatives as Fluorescent Chemosensors for Metal Ions''
  R. Miyamoto, J. Kawakami, S. Takahashi, S. Ito, M. Nagaki, H. Kitahara, J. Comp. Chem. Jpn. (JCCJ), (2006), 5, 19-22.

• ``Reactivity of superoxide ions (O₂^-) occluded in micropores of calcium aluminosilicate varied via substitution with transition metal ions''
  K. Sato, J. Iritani, R. Miyamoto, S. Fujita, K. Suzuki, M. Ohkawa, T. Mori, Stud. Surf. Sci. Catal. (Proc. of the 3rd International FEZA Conference), (2005), 158, 2001-2008.

• ``Synthesis and Characterization of Chromium(III) Octaphenylporphyrin Complexes with Various Axial Ligands''
  R. Harada, Y. Matsuda, H. Okawa, R. Miyamoto, S. Yamauchi, T. Kojima, Inorg. Chim. Acta, (2005), 358, 2489-2500.

• ``Ab Initio Molecular Orbital Study of Emission Mechanism of Fluorescent Chemosensors for Metal Ions''
  J. Kawakami, R. Miyamoto, Research Advances in Photochemistry & Photobiology, (2003), 2, 1-11.

• ``Ab Initio Molecular Orbital Study of Emission Mechanism of 2,6-Bis(quinolnecarboxy)methylpyridine as Fluorescent Chemosensors for Zinc and Cadmium Ions''
  J. Kawakami, R. Miyamoto, K. Kimura, K. Obata, M. Nagaki, H. Kitahara, J. Comp. Chem. Jpn. (JCCJ), (2003), 2, 57-62.

• ``EXAFS Study on the Local Structure of Gadolinium(III)-Nickel(II) bi-nuclear Complexes''
  S. Sudoh, T. Miyanaga, R. Miyamoto, Geotechnical Engineering: Environmental Challenges, 2, 728-730 (2002).

• ``Spectroscopic Study of the Coordination Sphere of the Gd(III) in the Gd(III)-M(II) Complexes with an Compartmental Ligand, where the Local Environment around Gd(III) is Controlled by M(II) (M(II) = Ni(II), Zn(II), and Vacancy)''
  R. Miyamoto, T. Sugai, S. Sudoh, Polyhedron, 21, 2127-2135 (2002).

• ``EPR Spectral Study of Gadolinium(III) Cryptate''
  R. Miyamoto, H. Sato, S. Sudoh, in ``EPR in the 21st Century (Proceedings of the 3rd Asia-Pacific EPR/ESR Symposium)'', A. Kawamori, J. Yamauchi, and H. Ohta, Eds., Elsevier, (2002), pp 316-321.

• ``Ab Initio Molecular Orbital Study of Complexing Behavior of N-Ethyl-1-naphthalenecarboxamide as Fluorescent Chemosensors for Alkali and Alkaline Earth Metal Ions''
  J. Kawakami, R. Miyamoto, A. Fukushi, K. Shimozaki, S. Itoh, J. Photochem. Photobiol. A: Chemistry, 146, 163-168 (2002).

• ``The Conformational Analysis of Organic Molecules by Theoretical Calculations''
  J. Kawakami, Y. Kawakami, R. Miyamoto, K. Nakamura, H. Kojima, Y. Tamai, and S. Ito, Recent Research Developments in Pure & Applied Chemistry, 4, 49-58 (2000).

• ``Correlation of Excimer Formation with Ground State Conformations: The Conformation Analysis of 1,2-Bis(1-naphthalenecarboxy)ethane by Ab Initio Molecular Orbital Calculations''
  J. Kawakami, R. Miyamoto, S. Itoh, JCPE Journal, 12, 25-32 (2000).

• ``EPR Spectra of Some Gadolinium(III) Complexes''
  R. Miyamoto, S. Sudoh, Modern Applications of EPR/ESR: From Biophysics to Materials Science --- Proceedings of the 1st Asia-Pacific EPR/ESR Symposium, C. Z. Rudowicz, K. N. Yu, H. Hiraoka, Eds., Springer-Verlag, Singapore, pp 256-259, (1998).

• ``EPR Studies of the Mixed-metal Cubane-type Complex Having a [Mo₃CuS₄(H₂O)₁₀]⁴⁺ Core''
  R. Miyamoto, S. Kawata, M. Iwaizumi, H. Akashi, T. Shibahara, Inorg. Chem., 36, 542-546 (1997).

• ``Magnetic Properties of Some Triangular Trinuclear Complexes of [Ru₂M(\mu-CH₃COO)₆(\mu₃-O)(py)₃]ⁿ⁺ with a Paramagnetic Ion M''
  H. Kobayashi, N. Uryu, I. Mogi, R. Miyamoto, Y. Ohba, M. Iwaizumi, Y. Sasaki, A. Ohto, M. Suwabe, T. Ito, Bull. Chem. Soc. Jpn., 69, 3163-3172 (1996).

• ``EPR Spectra of Gadolinium(III)-\beta-diketonate Complexes''
  R. Miyamoto, S. Sudoh, Bull. Chem. Soc. Jpn., 68, 3439-3443 (1995).

• ``Magnetic Properties of Some Triangular Trinuclear Complexes of [Ru₂M(\mu-CH₃COO)₆(\mu₃-O)(py)₃]ⁿ⁺ with a Diamagnetic Ion M''
  H. Kobayashi, N. Uryu, I. Mogi, R. Miyamoto, Y. Ohba, M. Iwaizumi, Y. Sasaki, A. Ohto, T. Ito, Bull. Chem. Soc. Jpn., 68, 2551-2558 (1995).

• ``Interplanar Interactions in the Triplet Dimers of Zn and Metal Free Complexes of Crowned Porphyrin and Phthalocyanine Studied by Time-resolved Electron Paramagnetic Resonance''
  R. Miyamoto, S. Yamauchi, N. Kobayashi, T. Osa, Y. Ohba, M. Iwaizumi, Coord. Chem. Rev., 132, 57-62 (1994).

• ``Angle-Selected ¹⁴N-ENDOR Study of Copper(II) Complexes with Distorted N₂S₂ and N₂O₂ Coordinating Structure''
  R. Miyamoto, Y. Ohba, M. Iwaizumi, Inorg. Chem., 31, 3138-3149 (1992).

• ``Nitrogen-14 ENDOR study on bis(2-hydroxylphenyl ketoxime) copper-63(II) complex''
  Y. Xu, D. Chen, C. Cheng, R. Miyamoto, Y. Ohba, M. Iwaizumi, C. Zhou, Y. Chen, Science in China, Series B: Chemistry, Life Sciences, & Earth Sciences, 36, 1052-1060 (1993).

• ``Spin-Spin Couplings in Copper Acetate Hydrate Dimer Studied by Single Crystal ¹³C ENDOR for Zinc-Doped Copper Acetate Monohydrate''
  S. Kita, K. Uchida, R. Miyamoto, M. Iwaizumi, Chem. Lett., (1992), 1329-1332.

• ``Studies on the ESR spectra and ENDOR spectra of nitrogen-15-labeled bis(2-hydroxyacetophenone oxime)-copper-63(II) complex''
  D. Chen, Y. Xu, R. Miyamoto, Y. Ohba, M. Iwaizumi, Y. Chen, C. Zhou, Huaxue Xuebao, 50, 691-697 (1992). (Chinese)

• ``Proton ENDOR Studies on Zinc-Doped Copper(II) Acetate Monohydrate Single Crystal''
  S. Kita, K. Uchida, R. Miyamoto, M. Iwaizumi, Bull. Chem. Soc. Jpn., 64, 3324-3328 (1991).

• ``Hyperfine Interactions of Coordinating Nitrogens in the Copper(II) Complexes Having a N₂S₂ Donor Set and Blue Copper Proteins''
  R. Miyamoto, Y. Ohba, and M. Iwaizumi, Inorg. Chem., 29, 3234-3238 (1990).

• ``¹⁴N ENDOR Study of the N₂S₂ Coordination Copper(II) Complex, Cu(sacen), Doped in Ni(sacen) and Zn(sacen).''
  R. Miyamoto, Y. Ohba, and M. Iwaizumi, Proc. of the International Workshop on Electron Magnetic Resonance of Disordered Systems, N. D. Yordanov, Ed., World Scientific, Singapore, pp 113-125, (1989).

• ``Structural Studies of Copper(II) Complexes with Biological Interest as Studied by Nitrogen ENDOR.''
  M. Iwaizumi, R. Miyamoto, and Y. Ohba, Proc. of the 10th National Conference on Molecular Spectroscopy, B. Jordanov, N. Kirov, P. Simova, Eds., World Scientific, Singapore, pp 499-513, (1989).

• ``歪んだ配位構造を持つ窒素配位銅(II)錯体の angle-selected ¹⁴N-ENDOR''
  宮本量, 博士論文, 東北大学, (1990).

• ``レアメタル便覧'', 足立吟也 監修, 丸善, (2011), ISBN978-4-621-08276-8.
• ``希土類とアクチノイドの化学'', S. A. Cotton 著, 足立吟也 監修, 足立吟也, 日夏幸雄, 宮本量 訳, 丸善&Wiley, (2008), ISBN978-4-621-07937-9.

• ``コンピュータでカガクする --- 分子分光学・分子構造・電子状態の研究''
  宮本 量, 弘前大学総合情報処理センター広報誌 HIROIN No.17, Oct. (2001), pp. 32-36.

• 自作のプログラム Z-matrix Editor ``KUMI'' および 分子量・元素分析値計算プログラム ``xmolwt'' が, メデディアラボの「Linux Science-Pack Vol. 1」に収録されました。(2001-06-25)

• ``Photophysical Properties of β-(1-Pyrenyl)ethyl p-Cyanobenzoate in Binary Solvents of Isooctane-Ethyl Acetate and Ethyl Acetate-Acetonitrile''
  J. Kawakami, J. Nakamura, M. Iwamura, J. Photochem. Photobiol. A: Chemistry, 140, 199-206 (2001).
  (Ab initio 計算担当, Acknowledgment に氏名記載)

• ``Study on the Local Structure of Lanthanoid Complex by Ln K-edge EXAFS''
  T. Miyanaga, S. Sudoh, R. Miyamoto, S. Ikeda, H. Kon, SPring-8 User Experiment Report, No.3, 17 (2000).

• "分子科学計算のための分子構造データ作成支援プログラムの開発"
  宮本 量, 弘前大学総合情報処理センター広報誌 HIROIN No.13, (1999), pp. 27-41.
  (平成 9 年度 弘前大学総合情報処理センター「研究開発費」成果報告)

• "(ミニファイル) 機器分析に用いられる略号: 磁気共鳴(IV), ESR"
  宮本 量, ぶんせき, No.12, (1997), pp. 997-998.

• "分子軌道計算の視覚化---量子化学計算支援プログラム群"
  宮本 量, 弘前大学総合情報処理センター広報誌 HIROIN No.9, Oct. (1997), pp. 2-7.

• ``EPR Studies of Some Rare Earth Complexes in Relation to Their Coordination Structures'',
  Ryo MIYAMOTO, Susumu SUDOH, in `New Development of Studies on Rare Earth Complexes, Report of a Priority Area Research Program', G. Adachi, T. Yamase, J. Inanaga, M. Komiyama, K. Machida, Eds., August (1997), pp 227-234.
  (文部省 科学研究費補助金 重点領域研究「希土類錯体の新展開」 研究成果総合報告書)

• "希土類錯体の配位構造と EPR スペクトル"
  宮本 量, 文部省 科学研究費補助金 重点領域研究「希土類錯体の新展開」 平成 7 年度研究成果報告書, March (1996), pp. 155-158.

• "結論から言うと"
  宮本 量, 大学生活とパソコン(新入生向けパンフレット), 弘前大学消費生活共同組合, March, (1997).

• "1st Asia-Pacific EPR/ESR Symposium に参加して"
  宮本 量, 希土類錯体領域ニュース No.9, March (1997), p. 150.

• "コンピュータは電子計算機か文房具か?"
  宮本 量, 弘前大学学園だより, 第110号 (1995).

• "(トピックス) スピンエコーを用いた銅錯体の構造化学"
  宮本 量, 化学と工業, 48(4), 532 (1995).

• "希土類錯体の局所構造の EPR による解析"
  宮本 量, 須藤 進, 文部省 科学研究費補助金 重点領域研究「希土類錯体の新展開」 平成 6 年度研究成果報告書, March (1995), pp. 191-194.

• "スピンによる量子化学演習"
  宮本 量, 希土類錯体領域ニュース No.2, November (1994), pp. 70-78.

• "Magnetic Properties of Oxygen Centered Trinuclear Ruthenium(III) and Rhodium(III) Complexes"
  H. Kobayashi, N. Uryu, A. Tokiwa, T. Yamaguti, Y. Sasaki, Bull. Chem. Soc. Jpn. (1992), 65, 198-202.
  (EPR 測定・解析と議論とを担当, Acknowledgment に氏名記載)

所属学会等 (Member of)

• 電子スピンサイエンス学会(2002)
• 日本化学プログラム交換機構(JCPE)(1993)/日本コンピュータ化学会(2002)
• 錯体化学研究会(1998)/錯体化学会(2001)
• DV-Xa研究協会(1996)
• 日本希土類学会(1994)
• 日本化学会(1987)